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Activation Of The Cooh Group Notes

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Activation Of The Cooh Group Revision

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NaN3 PCl5/SOCl2

R'-COOH

Mechanisms:

RCOOH + NaN3  RCON3 RCOOH + SOCl2  RCOCl + HCl RCOOH + PCl5  RCOCl + HCl RCOOH + DCC  O-acylisourea O-acylisourea + HOBt  RCOO-HOBt RCOOH + DCC + R'-OH  RCOOR' + dicyclohexylurea

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